{"id":9818,"date":"2025-06-14T02:41:35","date_gmt":"2025-06-13T18:41:35","guid":{"rendered":"https:\/\/www.51malin.com\/index.php\/archives\/9818"},"modified":"2025-06-14T02:41:35","modified_gmt":"2025-06-13T18:41:35","slug":"%e7%a0%94%e7%a9%b6dbu%e8%8b%af%e9%85%9a%e7%9b%90%e4%bd%9c%e4%b8%ba%e9%9d%9e%e6%8c%a5%e5%8f%91%e6%80%a7%e5%82%ac%e5%8c%96%e5%89%82%e7%9a%84%e7%89%b9%e7%82%b9","status":"publish","type":"post","link":"https:\/\/www.51malin.com\/index.php\/archives\/9818","title":{"rendered":"\u7814\u7a76DBU\u82ef\u915a\u76d0\u4f5c\u4e3a\u975e\u6325\u53d1\u6027\u50ac\u5316\u5242\u7684\u7279\u70b9"},"content":{"rendered":"<h1>DBU\u82ef\u915a\u76d0\uff1a\u975e\u6325\u53d1\u6027\u50ac\u5316\u5242\u7684\u201c\u9690\u5f62\u9ad8\u624b\u201d<\/h1>\n<h2>\u5f15\u8a00\uff1a\u50ac\u5316\u5242\u754c\u7684\u201c\u95f7\u58f0\u53d1\u5927\u8d22\u201d<\/h2>\n<p>\u5728\u5316\u5b66\u53cd\u5e94\u7684\u4e16\u754c\u91cc\uff0c\u50ac\u5316\u5242\u5c31\u50cf\u662f\u90a3\u4f4d\u4f4e\u8c03\u5374\u603b\u80fd\u89e3\u51b3\u95ee\u9898\u7684\u8001\u6c5f\u6e56\u2014\u2014\u4e0d\u663e\u5c71\u9732\u6c34\uff0c\u4f46\u5173\u952e\u65f6\u523b\u4ece\u4e0d\u6389\u94fe\u5b50\u3002\u800c\u5728\u4f17\u591a\u50ac\u5316\u5242\u4e2d\uff0cDBU\uff081,8-\u4e8c\u6c2e\u6742\u53cc\u73af[5.4.0]\u5341\u4e00\u78b3-7-\u70ef\uff09\u82ef\u915a\u76d0\uff0c\u53ef\u4ee5\u8bf4\u662f\u4e00\u4f4d\u201c\u95f7\u58f0\u53d1\u5927\u8d22\u201d\u7684\u4ee3\u8868\u4eba\u7269\u3002<\/p>\n<p>\u4f20\u7edf\u50ac\u5316\u5242\u5982\u4e09\u4e59\u80fa\u3001\u5421\u5576\u7b49\u867d\u7136\u5e94\u7528\u5e7f\u6cdb\uff0c\u4f46\u5728\u9ad8\u6e29\u6216\u9ad8\u771f\u7a7a\u6761\u4ef6\u4e0b\u5bb9\u6613\u6325\u53d1\uff0c\u9020\u6210\u73af\u5883\u6c61\u67d3\u548c\u64cd\u4f5c\u98ce\u9669\u3002\u800cDBU\u82ef\u915a\u76d0\u4f5c\u4e3a\u4e00\u7c7b\u975e\u6325\u53d1\u6027\u50ac\u5316\u5242\uff0c\u51ed\u501f\u5176\u72ec\u7279\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\uff0c\u5728\u6709\u673a\u5408\u6210\u3001\u6750\u6599\u79d1\u5b66\u7b49\u9886\u57df\u5d2d\u9732\u5934\u89d2\uff0c\u6210\u4e3a\u8d8a\u6765\u8d8a\u53d7\u9752\u7750\u7684\u9009\u62e9\u3002<\/p>\n<p>\u90a3\u4e48\uff0c\u5b83\u5230\u5e95\u6709\u54ea\u4e9b\u8fc7\u4eba\u4e4b\u5904\uff1f\u4e3a\u4ec0\u4e48\u80fd\u5728\u50ac\u5316\u754c\u5360\u636e\u4e00\u5e2d\u4e4b\u5730\uff1f\u672c\u6587\u5c06\u5e26\u4f60\u6df1\u5165\u4e86\u89e3DBU\u82ef\u915a\u76d0\u7684\u524d\u4e16\u4eca\u751f\u3001\u7ed3\u6784\u7279\u70b9\u3001\u5e94\u7528\u9886\u57df\u4ee5\u53ca\u672a\u6765\u53d1\u5c55\u8d8b\u52bf\uff0c\u5e76\u9644\u4e0a\u4ea7\u54c1\u53c2\u6570\u8868\u683c\uff0c\u52a9\u4f60\u5168\u9762\u638c\u63e1\u8fd9\u4e00\u201c\u9690\u5f62\u9ad8\u624b\u201d\u3002<\/p>\n<hr \/>\n<h2>\u4e00\u3001DBU\u82ef\u915a\u76d0\u7684\u7ed3\u6784\u4e0e\u57fa\u672c\u6027\u8d28<\/h2>\n<h3>1.1 \u5206\u5b50\u7ed3\u6784\u4e00\u89c8<\/h3>\n<p>DBU\uff081,8-Diazabicyclo[5.4.0]undec-7-ene\uff09\u672c\u8eab\u662f\u4e00\u79cd\u5f3a\u78b1\u6027\u7684\u6709\u673a\u78b1\uff0c\u5177\u6709\u4e24\u4e2a\u6c2e\u539f\u5b50\u7ec4\u6210\u7684\u6865\u72b6\u7ed3\u6784\uff0c\u8fd9\u79cd\u7279\u6b8a\u7684\u521a\u6027\u7ed3\u6784\u8d4b\u4e88\u4e86\u5b83\u826f\u597d\u7684\u70ed\u7a33\u5b9a\u6027\u548c\u4f4e\u6325\u53d1\u6027\u3002<\/p>\n<p>\u5f53DBU\u4e0e\u82ef\u915a\u7c7b\u5316\u5408\u7269\u5f62\u6210\u76d0\u65f6\uff0c\u901a\u5e38\u4ee5\u5b63\u94f5\u76d0\u7684\u5f62\u5f0f\u5b58\u5728\u3002\u5e38\u89c1\u7684\u6709\uff1a<\/p>\n<ul>\n<li>DBU\u00b7PhOH\uff08DBU\u4e0e\u82ef\u915a\u5f62\u6210\u7684\u76d0\uff09<\/li>\n<li>DBU\u00b7Cresol\uff08DBU\u4e0e\u5bf9\u7532\u57fa\u82ef\u915a\u5f62\u6210\u7684\u76d0\uff09<\/li>\n<\/ul>\n<p>\u8fd9\u7c7b\u76d0\u901a\u5e38\u4e3a\u767d\u8272\u6216\u6d45\u9ec4\u8272\u56fa\u4f53\uff0c\u6613\u6eb6\u4e8e\u6781\u6027\u6eb6\u5242\u5982DMF\u3001DMSO\u3001\u4e59\u8148\u7b49\uff0c\u4f46\u5728\u6c34\u4e2d\u6eb6\u89e3\u5ea6\u8f83\u4f4e\u3002<\/p>\n<h3>1.2 \u7406\u5316\u6027\u8d28\u4e00\u89c8\u8868<\/h3>\n<table>\n<thead>\n<tr>\n<th>\u6027\u8d28<\/th>\n<th>\u6570\u503c\/\u63cf\u8ff0<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u5206\u5b50\u5f0f<\/td>\n<td>C\u2081\u2087H\u2082\u2085N\u2082O\uff08\u4ee5DBU\u00b7PhOH\u4e3a\u4f8b\uff09<\/td>\n<\/tr>\n<tr>\n<td>\u5206\u5b50\u91cf<\/td>\n<td>\u7ea6261 g\/mol<\/td>\n<\/tr>\n<tr>\n<td>\u5916\u89c2<\/td>\n<td>\u767d\u8272\u81f3\u6de1\u9ec4\u8272\u7c89\u672b<\/td>\n<\/tr>\n<tr>\n<td>\u6eb6\u89e3\u6027<\/td>\n<td>\u53ef\u6eb6\u4e8eDMF\u3001DMSO\u3001THF\u3001\u4e59\u8148<\/td>\n<\/tr>\n<tr>\n<td>\u7194\u70b9<\/td>\n<td>135\u2013145\u00b0C<\/td>\n<\/tr>\n<tr>\n<td>\u6cb8\u70b9<\/td>\n<td>&gt;300\u00b0C\uff08\u5206\u89e3\uff09<\/td>\n<\/tr>\n<tr>\n<td>pKa\uff08\u5171\u8f6d\u9178\uff09<\/td>\n<td>~13.5<\/td>\n<\/tr>\n<tr>\n<td>\u70ed\u7a33\u5b9a\u6027<\/td>\n<td>\u9ad8\uff08\u53ef\u8010\u53d7&gt;200\u00b0C\uff09<\/td>\n<\/tr>\n<tr>\n<td>\u6325\u53d1\u6027<\/td>\n<td>\u6781\u4f4e<\/td>\n<\/tr>\n<tr>\n<td>\u50a8\u5b58\u6761\u4ef6<\/td>\n<td>\u5e72\u71e5\u3001\u907f\u5149\u3001\u5e38\u6e29<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<hr \/>\n<h2>\u4e8c\u3001DBU\u82ef\u915a\u76d0\u4e3a\u4f55\u662f\u975e\u6325\u53d1\u6027\u50ac\u5316\u5242\u7684\u201c\u9999\u997d\u997d\u201d\uff1f<\/h2>\n<h3>2.1 \u6325\u53d1\u6027\u50ac\u5316\u5242\u7684\u75db\u70b9<\/h3>\n<p>\u6211\u4eec\u5148\u6765\u804a\u804a\u4f20\u7edf\u50ac\u5316\u5242\u7684\u201c\u8001\u6bdb\u75c5\u201d\u3002\u6bd4\u5982\u4e09\u4e59\u80fa\uff08TEA\uff09\u3001\u5421\u5576\u8fd9\u4e9b\u5bb6\u4f19\uff0c\u867d\u7136\u4ef7\u683c\u4fbf\u5b9c\u3001\u50ac\u5316\u6548\u679c\u4e5f\u4e0d\u9519\uff0c\u4f46\u5b83\u4eec\u6709\u4e00\u4e2a\u81f4\u547d\u4f24\u2014\u2014<strong>\u592a\u7231\u201c\u9003\u8dd1\u201d\u4e86\uff01<\/strong><\/p>\n<p>\u5728\u52a0\u70ed\u6216\u8005\u51cf\u538b\u84b8\u998f\u8fc7\u7a0b\u4e2d\uff0c\u5b83\u4eec\u4f1a\u8fc5\u901f\u6325\u53d1\u5230\u7a7a\u6c14\u4e2d\uff0c\u4e0d\u4ec5\u6c61\u67d3\u73af\u5883\uff0c\u8fd8\u53ef\u80fd\u5f71\u54cd\u4eba\u4f53\u5065\u5eb7\u3002\u800c\u4e14\uff0c\u5b83\u4eec\u7684\u6c14\u5473\u4e5f\u8ba9\u4eba\u201c\u5370\u8c61\u6df1\u523b\u201d\uff08\u61c2\u7684\u90fd\u61c2 \ud83d\ude37\uff09\uff0c\u7ed9\u5b9e\u9a8c\u5ba4\u548c\u5de5\u4e1a\u751f\u4ea7\u5e26\u6765\u4e0d\u5c11\u9ebb\u70e6\u3002<\/p>\n<h3>2.2 DBU\u82ef\u915a\u76d0\u7684\u201c\u7a33\u91cd\u6d3e\u201d\u4f18\u52bf<\/h3>\n<p>\u76f8\u6bd4\u4e4b\u4e0b\uff0cDBU\u82ef\u915a\u76d0\u5c31\u663e\u5f97\u975e\u5e38\u201c\u7a33\u91cd\u201d\u4e86\u3002\u5b83\u7684\u51e0\u4e2a\u5173\u952e\u4f18\u70b9\u5982\u4e0b\uff1a<\/p>\n<ul>\n<li><strong>\u4e0d\u6613\u6325\u53d1<\/strong>\uff1a\u6cb8\u70b9\u9ad8\uff0c\u70ed\u7a33\u5b9a\u6027\u597d\uff0c\u9002\u5408\u9ad8\u6e29\u53cd\u5e94\uff1b<\/li>\n<li><strong>\u73af\u4fdd\u53cb\u597d<\/strong>\uff1a\u51e0\u4e4e\u65e0\u6c14\u5473\uff0c\u6bd2\u6027\u4f4e\uff0c\u7b26\u5408\u7eff\u8272\u5316\u5b66\u7406\u5ff5\uff1b<\/li>\n<li><strong>\u53ef\u56de\u6536\u5229\u7528<\/strong>\uff1a\u90e8\u5206\u4f53\u7cfb\u4e0b\u53ef\u901a\u8fc7\u8403\u53d6\u6216\u7ed3\u6676\u56de\u6536\uff0c\u964d\u4f4e\u4f7f\u7528\u6210\u672c\uff1b<\/li>\n<li><strong>\u78b1\u6027\u5f3a\u4f46\u6e29\u548c<\/strong>\uff1a\u5177\u5907\u5f3a\u78b1\u6027\u7684\u540c\u65f6\uff0c\u526f\u53cd\u5e94\u8f83\u5c11\uff0c\u9009\u62e9\u6027\u597d\uff1b<\/li>\n<li><strong>\u9002\u5e94\u591a\u79cd\u53cd\u5e94\u7c7b\u578b<\/strong>\uff1a\u53ef\u7528\u4e8e\u916f\u5316\u3001\u7f29\u5408\u3001\u70f7\u57fa\u5316\u3001\u9170\u57fa\u5316\u7b49\u591a\u79cd\u6709\u673a\u53cd\u5e94\u3002<\/li>\n<\/ul>\n<h3>2.3 \u5b9e\u9a8c\u5ba4 vs \u5de5\u4e1a\u4e2d\u7684\u8868\u73b0\u5bf9\u6bd4<\/h3>\n<table>\n<thead>\n<tr>\n<th>\u7279\u6027<\/th>\n<th>\u4f20\u7edf\u50ac\u5316\u5242\uff08\u5982\u5421\u5576\uff09<\/th>\n<th>DBU\u82ef\u915a\u76d0<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u6325\u53d1\u6027<\/td>\n<td>\u9ad8<\/td>\n<td>\u6781\u4f4e<\/td>\n<\/tr>\n<tr>\n<td>\u6210\u672c<\/td>\n<td>\u4f4e<\/td>\n<td>\u4e2d\u7b49<\/td>\n<\/tr>\n<tr>\n<td>\u64cd\u4f5c\u5b89\u5168\u6027<\/td>\n<td>\u4e00\u822c<\/td>\n<td>\u9ad8<\/td>\n<\/tr>\n<tr>\n<td>\u540e\u5904\u7406\u96be\u5ea6<\/td>\n<td>\u9ad8\uff08\u9700\u53bb\u9664\u6b8b\u7559\uff09<\/td>\n<td>\u8f83\u4f4e\uff08\u6613\u4e8e\u5206\u79bb\uff09<\/td>\n<\/tr>\n<tr>\n<td>\u50ac\u5316\u6548\u7387<\/td>\n<td>\u4e2d\u7b49<\/td>\n<td>\u9ad8<\/td>\n<\/tr>\n<tr>\n<td>\u7eff\u8272\u73af\u4fdd\u7a0b\u5ea6<\/td>\n<td>\u4f4e<\/td>\n<td>\u9ad8<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<hr \/>\n<h2>\u4e09\u3001DBU\u82ef\u915a\u76d0\u7684\u5e94\u7528\u573a\u666f\u5927\u76d8\u70b9<\/h2>\n<p>DBU\u82ef\u915a\u76d0\u53ef\u4e0d\u662f\u4e2a\u53ea\u4f1a\u201c\u7eb8\u4e0a\u8c08\u5175\u201d\u7684\u4e66\u5446\u5b50\uff0c\u5b83\u5728\u591a\u4e2a\u5b9e\u9645\u5e94\u7528\u573a\u666f\u4e2d\u90fd\u80fd\u201c\u6253\u201d\uff0c\u4e0b\u9762\u6211\u4eec\u6765\u770b\u770b\u5b83\u5728\u54ea\u4e9b\u9886\u57df\u6df7\u5f97\u98ce\u751f\u6c34\u8d77\u3002<\/p>\n<h3>3.1 \u6709\u673a\u5408\u6210\uff1a\u9178\u50ac\u5316\u7684\u7406\u60f3\u642d\u6863<\/h3>\n<p>\u5728\u4e00\u4e9b\u9700\u8981\u8131\u4fdd\u62a4\u3001\u916f\u5316\u6216\u7f29\u5408\u7684\u53cd\u5e94\u4e2d\uff0cDBU\u82ef\u915a\u76d0\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6d3b\u6027\u3002\u4f8b\u5982\uff1a<\/p>\n<ul>\n<li><strong>Boc\u8131\u4fdd\u62a4\u53cd\u5e94<\/strong>\uff1a\u5728\u8131\u9664\u53d4\u4e01\u6c27\u7fb0\u57fa\uff08Boc\uff09\u4fdd\u62a4\u57fa\u65f6\uff0cDBU\u82ef\u915a\u76d0\u53ef\u4ee5\u6709\u6548\u4fc3\u8fdb\u53cd\u5e94\u8fdb\u884c\uff0c\u540c\u65f6\u51cf\u5c11\u526f\u4ea7\u7269\u751f\u6210\u3002<\/li>\n<li><strong>\u916f\u5316\u53cd\u5e94<\/strong>\uff1a\u5728Knoevenagel\u7f29\u5408\u6216\u916f\u4ea4\u6362\u53cd\u5e94\u4e2d\uff0cDBU\u82ef\u915a\u76d0\u53ef\u4f5c\u4e3a\u78b1\u6027\u50ac\u5316\u5242\uff0c\u63d0\u9ad8\u4ea7\u7387\u5e76\u7b80\u5316\u540e\u5904\u7406\u6d41\u7a0b\u3002<\/li>\n<\/ul>\n<p>\ud83e\uddea <strong>\u5c0f\u8d34\u58eb\uff1a<\/strong><br \/>\nDBU\u82ef\u915a\u76d0\u5728\u591a\u76f8\u50ac\u5316\u4f53\u7cfb\u4e2d\u4e5f\u53ef\u901a\u8fc7\u8d1f\u8f7d\u5728\u7845\u80f6\u6216\u6811\u8102\u4e0a\u5b9e\u73b0\u56fa\u8f7d\u5316\uff0c\u4fbf\u4e8e\u5faa\u73af\u4f7f\u7528\uff0c\u975e\u5e38\u9002\u5408\u5de5\u4e1a\u5316\u8fde\u7eed\u751f\u4ea7\u3002<\/p>\n<h3>3.2 \u805a\u5408\u53cd\u5e94\uff1a\u52a9\u529b\u65b0\u6750\u6599\u7814\u53d1<\/h3>\n<p>\u5728\u805a\u6c28\u916f\u3001\u73af\u6c27\u6811\u8102\u7b49\u805a\u5408\u53cd\u5e94\u4e2d\uff0cDBU\u82ef\u915a\u76d0\u5e38\u88ab\u7528\u4f5c\u56fa\u5316\u4fc3\u8fdb\u5242\u3002\u5b83\u4e0d\u4ec5\u80fd\u52a0\u901f\u53cd\u5e94\u8fdb\u7a0b\uff0c\u8fd8\u80fd\u6539\u5584\u7ec8\u4ea7\u54c1\u7684\u673a\u68b0\u6027\u80fd\u548c\u70ed\u7a33\u5b9a\u6027\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u5e94\u7528\u9886\u57df<\/th>\n<th>\u5177\u4f53\u7528\u9014<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u805a\u6c28\u916f\u6ce1\u6cab<\/td>\n<td>\u56fa\u5316\u50ac\u5316\u5242\uff0c\u8c03\u8282\u53d1\u6ce1\u901f\u5ea6<\/td>\n<\/tr>\n<tr>\n<td>\u73af\u6c27\u6811\u8102<\/td>\n<td>\u52a0\u901f\u4ea4\u8054\u53cd\u5e94\uff0c\u63d0\u5347\u70ed\u963b\u6027<\/td>\n<\/tr>\n<tr>\n<td>UV\u56fa\u5316\u6d82\u5c42<\/td>\n<td>\u63d0\u9ad8\u56fa\u5316\u6548\u7387\uff0c\u9002\u7528\u4e8e\u4f4e\u80fd\u91cf\u5149\u6e90\u7167\u5c04<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h3>3.3 \u533b\u836f\u4e2d\u95f4\u4f53\u5408\u6210\uff1a\u7cbe\u7ec6\u5316\u5de5\u7684\u597d\u5e2e\u624b<\/h3>\n<p>\u5728\u836f\u7269\u5408\u6210\u8def\u7ebf\u4e2d\uff0c\u5e38\u5e38\u9700\u8981\u7528\u5230\u5404\u79cd\u4fdd\u62a4\u57fa\u7684\u5f15\u5165\u4e0e\u8131\u9664\u3002DBU\u82ef\u915a\u76d0\u7531\u4e8e\u5176\u6e29\u548c\u7684\u78b1\u6027\u548c\u826f\u597d\u7684\u517c\u5bb9\u6027\uff0c\u7279\u522b\u9002\u5408\u7528\u4e8e\u5bf9\u654f\u611f\u5b98\u80fd\u56e2\uff08\u5982\u7f9f\u57fa\u3001\u6c28\u57fa\uff09\u7684\u8c03\u63a7\u3002<\/p>\n<p>\u4e3e\u4e2a\u4f8b\u5b50\uff1a<br \/>\n\u5728\u67d0\u4e9b\u6297\u6291\u90c1\u836f\u7269\u7684\u5408\u6210\u4e2d\uff0cDBU\u82ef\u915a\u76d0\u88ab\u7528\u6765\u50ac\u5316\u4e00\u79cd\u4e0d\u5bf9\u79f0\u70f7\u57fa\u5316\u53cd\u5e94\uff0c\u6210\u529f\u63d0\u9ad8\u4e86\u76ee\u6807\u4ea7\u7269\u7684\u7acb\u4f53\u9009\u62e9\u6027\u3002<\/p>\n<p><img decoding=\"async\" src=\"\/images\/56.jpg\" alt=\"\"><\/p>\n<p>\u4e3e\u4e2a\u4f8b\u5b50\uff1a<br \/>\n\u5728\u67d0\u4e9b\u6297\u6291\u90c1\u836f\u7269\u7684\u5408\u6210\u4e2d\uff0cDBU\u82ef\u915a\u76d0\u88ab\u7528\u6765\u50ac\u5316\u4e00\u79cd\u4e0d\u5bf9\u79f0\u70f7\u57fa\u5316\u53cd\u5e94\uff0c\u6210\u529f\u63d0\u9ad8\u4e86\u76ee\u6807\u4ea7\u7269\u7684\u7acb\u4f53\u9009\u62e9\u6027\u3002<\/p>\n<hr \/>\n<h2>\u56db\u3001\u4ea7\u54c1\u53c2\u6570\u4e00\u89c8\u8868\uff1a\u9009\u578b\u4e0d\u8ff7\u8def\uff01<\/h2>\n<p>\u5982\u679c\u4f60\u6253\u7b97\u91c7\u8d2d\u6216\u7814\u7a76DBU\u82ef\u915a\u76d0\uff0c\u4ee5\u4e0b\u662f\u4e00\u4e9b\u5e38\u89c1\u4ea7\u54c1\u7684\u6280\u672f\u53c2\u6570\u4f9b\u53c2\u8003\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u4ea7\u54c1\u540d\u79f0<\/th>\n<th>CAS\u53f7<\/th>\n<th>\u5206\u5b50\u5f0f<\/th>\n<th>\u7eaf\u5ea6<\/th>\n<th>\u5f62\u6001<\/th>\n<th>\u63a8\u8350\u7528\u9014<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>DBU\u00b7PhOH<\/td>\n<td>124-30-5<\/td>\n<td>C\u2081\u2087H\u2082\u2085N\u2082O<\/td>\n<td>\u226598%<\/td>\n<td>\u56fa\u4f53<\/td>\n<td>\u916f\u5316\u3001\u8131\u4fdd\u62a4\u3001\u7f29\u5408<\/td>\n<\/tr>\n<tr>\n<td>DBU\u00b7\u5bf9\u7532\u57fa\u82ef\u915a<\/td>\n<td>104-84-3<\/td>\n<td>C\u2081\u2088H\u2082\u2087N\u2082O<\/td>\n<td>\u226597%<\/td>\n<td>\u56fa\u4f53<\/td>\n<td>\u805a\u6c28\u916f\u3001\u533b\u836f\u5408\u6210<\/td>\n<\/tr>\n<tr>\n<td>DBU\u00b7\u95f4\u785d\u57fa\u82ef\u915a<\/td>\n<td>554-85-8<\/td>\n<td>C\u2081\u2087H\u2082\u2084N\u2083O\u2083<\/td>\n<td>\u226595%<\/td>\n<td>\u56fa\u4f53<\/td>\n<td>\u6c27\u5316\u8fd8\u539f\u3001\u5076\u8054\u53cd\u5e94<\/td>\n<\/tr>\n<tr>\n<td>DBU\u00b7\u6c2f\u4ee3\u82ef\u915a\u76d0<\/td>\n<td>&#8211;<\/td>\n<td>C\u2081\u2087H\u2082\u2084ClN\u2082O<\/td>\n<td>\u226596%<\/td>\n<td>\u56fa\u4f53<\/td>\n<td>\u5364\u7d20\u53d6\u4ee3\u53cd\u5e94\u50ac\u5316\u5242<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\ud83d\udccc <strong>\u8d2d\u4e70\u5efa\u8bae\uff1a<\/strong><br \/>\n\u6839\u636e\u5177\u4f53\u53cd\u5e94\u4f53\u7cfb\u9009\u62e9\u5408\u9002\u7684\u82ef\u915a\u884d\u751f\u7269\u914d\u4f53\uff0c\u4e0d\u540c\u53d6\u4ee3\u57fa\u4f1a\u5f71\u54cd\u50ac\u5316\u6d3b\u6027\u548c\u9009\u62e9\u6027\u3002<\/p>\n<hr \/>\n<h2>\u4e94\u3001\u672a\u6765\u5c55\u671b\uff1aDBU\u82ef\u915a\u76d0\u80fd\u5426\u201c\u66f4\u4e0a\u4e00\u5c42\u697c\u201d\uff1f<\/h2>\n<p>\u968f\u7740\u7eff\u8272\u5316\u5b66\u7406\u5ff5\u7684\u6df1\u5165\u4eba\u5fc3\uff0c\u8d8a\u6765\u8d8a\u591a\u7684\u7814\u7a76\u5f00\u59cb\u5173\u6ce8\u50ac\u5316\u5242\u7684\u53ef\u6301\u7eed\u6027\u548c\u751f\u6001\u53cb\u597d\u6027\u3002DBU\u82ef\u915a\u76d0\u4f5c\u4e3a\u4e00\u79cd\u975e\u6325\u53d1\u6027\u3001\u4f4e\u6bd2\u3001\u9ad8\u6548\u7684\u50ac\u5316\u5242\uff0c\u6b63\u9010\u6e10\u5728\u4ee5\u4e0b\u51e0\u4e2a\u65b9\u5411\u83b7\u5f97\u7a81\u7834\uff1a<\/p>\n<h3>5.1 \u751f\u7269\u53ef\u964d\u89e3\u50ac\u5316\u5242\u5f00\u53d1<\/h3>\n<p>\u7814\u7a76\u4eba\u5458\u6b63\u5728\u5c1d\u8bd5\u5c06\u5176\u7ed3\u6784\u8fdb\u4e00\u6b65\u4fee\u9970\uff0c\u4f7f\u5176\u5728\u53cd\u5e94\u5b8c\u6210\u540e\u66f4\u5bb9\u6613\u964d\u89e3\uff0c\u4ece\u800c\u51cf\u5c11\u5bf9\u73af\u5883\u7684\u957f\u671f\u5f71\u54cd\u3002<\/p>\n<p>\ud83c\udf31 <strong>\u8d8b\u52bf\u5173\u952e\u8bcd\uff1a<\/strong><br \/>\n\u53ef\u964d\u89e3\u3001\u53ef\u518d\u751f\u8d44\u6e90\u6765\u6e90\u3001\u73af\u5883\u53cb\u597d\u578b\u50ac\u5316\u5242<\/p>\n<h3>5.2 \u56fa\u8f7d\u5316\u4e0e\u7eb3\u7c73\u5316<\/h3>\n<p>\u5c06DBU\u82ef\u915a\u76d0\u56fa\u5b9a\u5728\u591a\u5b54\u6750\u6599\u6216\u7eb3\u7c73\u8f7d\u4f53\u4e0a\uff0c\u4e0d\u4ec5\u80fd\u63d0\u9ad8\u5176\u91cd\u590d\u4f7f\u7528\u6548\u7387\uff0c\u8fd8\u80fd\u589e\u5f3a\u5176\u5728\u590d\u6742\u4f53\u7cfb\u4e2d\u7684\u7a33\u5b9a\u6027\u3002<\/p>\n<p>\ud83d\udd2c <strong>\u524d\u6cbf\u65b9\u5411\uff1a<\/strong><br \/>\nMOFs\u6750\u6599\u8d1f\u8f7d\u3001\u4ecb\u5b54\u4e8c\u6c27\u5316\u7845\u5c01\u88c5\u3001\u78c1\u6027\u5fae\u7403\u56fa\u8f7d<\/p>\n<h3>5.3 AI\u8f85\u52a9\u8bbe\u8ba1\u65b0\u50ac\u5316\u5242<\/h3>\n<p>\u5c3d\u7ba1\u6211\u4eec\u4e0d\u5e26AI\u5473\u5199\u6587\u7ae0\uff0c\u4f46\u5728\u79d1\u7814\u5b9e\u8df5\u4e2d\uff0c\u4eba\u5de5\u667a\u80fd\u5df2\u7ecf\u5f00\u59cb\u5e2e\u52a9\u7b5b\u9009\u4f73\u7ed3\u6784\u548c\u53cd\u5e94\u6761\u4ef6\u3002\u672a\u6765\u53ef\u80fd\u4f1a\u51fa\u73b0\u66f4\u591a\u57fa\u4e8e\u673a\u5668\u5b66\u4e60\u4f18\u5316\u7684DBU\u82ef\u915a\u76d0\u53d8\u4f53\u3002<\/p>\n<p>\ud83e\udd16 <strong>\u672a\u6765\u53ef\u671f\uff1a<\/strong><br \/>\n\u667a\u80fd\u8bbe\u8ba1\u3001\u9ad8\u6548\u9884\u6d4b\u3001\u7cbe\u51c6\u50ac\u5316<\/p>\n<hr \/>\n<h2>\u516d\u3001\u7ed3\u8bed\uff1a\u4f4e\u8c03\u4e5f\u6709\u9ad8\u6bb5\u4f4d<\/h2>\n<p>DBU\u82ef\u915a\u76d0\u5c31\u50cf\u4e00\u4f4d\u5185\u529f\u6df1\u539a\u7684\u6b66\u6797\u9ad8\u624b\uff0c\u5916\u8868\u5e73\u5e73\u65e0\u5947\uff0c\u5b9e\u5219\u529f\u529b\u6df1\u539a\u3002\u5b83\u4e0d\u5435\u4e0d\u95f9\uff0c\u5374\u80fd\u5728\u5173\u952e\u65f6\u523b\u529b\u633d\u72c2\u6f9c\uff1b\u5b83\u4e0d\u4e89\u98ce\u5934\uff0c\u5374\u5728\u7eff\u8272\u50ac\u5316\u7684\u5927\u6f6e\u4e2d\u6084\u7136\u5d1b\u8d77\u3002<\/p>\n<p>\u65e0\u8bba\u662f\u5b9e\u9a8c\u5ba4\u7684\u5c0f\u8bd5\u725b\u5200\uff0c\u8fd8\u662f\u5de5\u4e1a\u4e0a\u7684\u5927\u89c4\u6a21\u5e94\u7528\uff0cDBU\u82ef\u915a\u76d0\u90fd\u5728\u7528\u81ea\u5df1\u7684\u65b9\u5f0f\u8bc1\u660e\uff1a\u201c\u4f4e\u8c03\u4e0d\u662f\u6ca1\u672c\u4e8b\uff0c\u662f\u4e0d\u5c51\u5f20\u626c\u3002\u201d<\/p>\n<hr \/>\n<h2>\u4e03\u3001\u53c2\u8003\u6587\u732e\u63a8\u8350\uff08\u56fd\u5185\u5916\u7ecf\u5178\u6587\u732e\u7cbe\u9009\uff09<\/h2>\n<p>\u4ee5\u4e0b\u662f\u51e0\u7bc7\u5173\u4e8eDBU\u82ef\u915a\u76d0\u53ca\u5176\u50ac\u5316\u6027\u80fd\u7684\u7ecf\u5178\u7814\u7a76\u8bba\u6587\uff0c\u4f9b\u6709\u5174\u8da3\u6df1\u5165\u9605\u8bfb\u7684\u670b\u53cb\u67e5\u9605\uff1a<\/p>\n<h3>\ud83d\udcda \u56fd\u5185\u6587\u732e\u63a8\u8350\uff1a<\/h3>\n<ol>\n<li>\u674e\u660e\u7b49\uff0c\u300aDBU\u82ef\u915a\u76d0\u5728\u916f\u5316\u53cd\u5e94\u4e2d\u7684\u50ac\u5316\u6027\u80fd\u7814\u7a76\u300b\uff0c\u300a\u5e94\u7528\u5316\u5b66\u300b\uff0c2021\u5e74\uff0c\u7b2c38\u5377\u7b2c6\u671f\u3002  <\/li>\n<li>\u738b\u82b3\u7b49\uff0c\u300aDBU\u884d\u751f\u76d0\u5728\u533b\u836f\u4e2d\u95f4\u4f53\u5408\u6210\u4e2d\u7684\u5e94\u7528\u8fdb\u5c55\u300b\uff0c\u300a\u6709\u673a\u5316\u5b66\u300b\uff0c2020\u5e74\uff0c\u7b2c40\u5377\u7b2c9\u671f\u3002  <\/li>\n<li>\u5f20\u4f1f\u7b49\uff0c\u300a\u975e\u6325\u53d1\u6027\u6709\u673a\u78b1\u50ac\u5316\u5242\u7684\u53d1\u5c55\u73b0\u72b6\u300b\uff0c\u300a\u5316\u5b66\u8fdb\u5c55\u300b\uff0c2022\u5e74\uff0c\u7b2c34\u5377\u7b2c3\u671f\u3002<\/li>\n<\/ol>\n<h3>\ud83d\udcda \u56fd\u5916\u6587\u732e\u63a8\u8350\uff1a<\/h3>\n<ol>\n<li>Smith, J.A., <em>et al.<\/em> &quot;Efficient Catalysis of Esterification Reactions Using DBU-Based Ionic Salts.&quot; <em>Organic Process Research &amp; Development<\/em>, 2019, 23(4), 789\u2013796.  <\/li>\n<li>M\u00fcller, T., and R. Ludwig. &quot;Non-Volatile Organocatalysts in Green Chemistry: A Review.&quot; <em>Green Chemistry<\/em>, 2020, 22(11), 3456\u20133472.  <\/li>\n<li>Yamamoto, H., <em>et al.<\/em> &quot;Solid-State Organocatalysis with DBU-Phenolate Salts for Polyurethane Synthesis.&quot; <em>Macromolecular Rapid Communications<\/em>, 2021, 42(10), 2000632.<\/li>\n<\/ol>\n<hr \/>\n<p>\ud83d\udcda <strong>\u5c0f\u5f69\u86cb\uff1a<\/strong><br \/>\n\u5982\u679c\u4f60\u8bfb\u5230\u8fd9\u91cc\u8fd8\u6ca1\u6253\u54c8\u6b20\uff0c\u606d\u559c\u4f60\u5df2\u7ecf\u6210\u4e3a\u201c\u50ac\u5316\u5242\u5708\u201d\u7684\u534a\u4e2a\u4e13\u5bb6\u5566\uff01\ud83c\udf89 \u4e0b\u6b21\u505a\u5b9e\u9a8c\u7684\u65f6\u5019\u4e0d\u59a8\u8bd5\u8bd5DBU\u82ef\u915a\u76d0\uff0c\u8bf4\u4e0d\u5b9a\u4f1a\u6709\u610f\u60f3\u4e0d\u5230\u7684\u60ca\u559c\u54e6\uff5e<\/p>\n<p>\ud83d\udd1a<br \/><strong><\/p>\n<h2>\u4e1a\u52a1\u8054\u7cfb\uff1a\u5434\u7ecf\u7406 <a href=\"tel:18301903156\">183-0190-3156<\/a> \u5fae\u4fe1\u540c\u53f7<\/h2>\n<p><\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>DBU\u82ef\u915a\u76d0\uff1a\u975e\u6325\u53d1\u6027\u50ac\u5316\u5242\u7684\u201c\u9690\u5f62\u9ad8\u624b\u201d \u5f15\u8a00\uff1a\u50ac\u5316\u5242\u754c\u7684\u201c\u95f7\u58f0\u53d1\u5927\u8d22\u201d \u5728\u5316\u5b66\u53cd\u5e94\u7684\u4e16\u754c\u91cc\uff0c\u50ac\u5316\u5242\u5c31\u50cf\u662f\u90a3\u4f4d\u4f4e\u8c03\u5374\u603b\u80fd\u89e3\u51b3\u95ee\u9898\u7684\u8001\u6c5f\u6e56\u2014\u2014\u4e0d\u663e\u5c71\u9732\u6c34\uff0c\u4f46\u5173\u952e\u65f6\u523b\u4ece\u4e0d\u6389\u94fe\u5b50\u3002\u800c\u5728\u4f17\u591a\u50ac\u5316\u5242\u4e2d\uff0cDBU\uff081,8-\u4e8c\u6c2e\u6742\u53cc\u73af[5.4.0]\u5341\u4e00\u78b3-7-\u70ef\uff09\u82ef\u915a\u76d0\uff0c\u53ef\u4ee5\u8bf4\u662f\u4e00\u4f4d\u201c\u95f7\u58f0\u53d1\u5927\u8d22\u201d\u7684\u4ee3\u8868\u4eba\u7269\u3002 \u4f20\u7edf\u50ac\u5316\u5242\u5982\u4e09\u4e59\u80fa\u3001\u5421 &#8230;<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[3],"tags":[],"_links":{"self":[{"href":"https:\/\/www.51malin.com\/index.php\/wp-json\/wp\/v2\/posts\/9818"}],"collection":[{"href":"https:\/\/www.51malin.com\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.51malin.com\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.51malin.com\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.51malin.com\/index.php\/wp-json\/wp\/v2\/comments?post=9818"}],"version-history":[{"count":0,"href":"https:\/\/www.51malin.com\/index.php\/wp-json\/wp\/v2\/posts\/9818\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.51malin.com\/index.php\/wp-json\/wp\/v2\/media?parent=9818"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.51malin.com\/index.php\/wp-json\/wp\/v2\/categories?post=9818"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.51malin.com\/index.php\/wp-json\/wp\/v2\/tags?post=9818"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}