{"id":9816,"date":"2025-06-14T02:33:09","date_gmt":"2025-06-13T18:33:09","guid":{"rendered":"https:\/\/www.51malin.com\/index.php\/archives\/9816"},"modified":"2025-06-14T02:33:09","modified_gmt":"2025-06-13T18:33:09","slug":"%e5%88%86%e6%9e%90dbu%e8%8b%af%e9%85%9a%e7%9b%90%e7%9a%84%e5%82%ac%e5%8c%96%e6%95%88%e7%8e%87%e4%b8%8e%e8%a1%a8%e7%9a%ae%e5%9b%ba%e5%8c%96%e4%bd%9c%e7%94%a8","status":"publish","type":"post","link":"https:\/\/www.51malin.com\/index.php\/archives\/9816","title":{"rendered":"\u5206\u6790DBU\u82ef\u915a\u76d0\u7684\u50ac\u5316\u6548\u7387\u4e0e\u8868\u76ae\u56fa\u5316\u4f5c\u7528"},"content":{"rendered":"<h1>DBU\u82ef\u915a\u76d0\uff1a\u50ac\u5316\u6548\u7387\u4e0e\u8868\u76ae\u56fa\u5316\u4f5c\u7528\u7684\u5947\u5999\u4e4b\u65c5<\/h1>\n<p>\u5728\u5316\u5b66\u7684\u4e16\u754c\u91cc\uff0c\u6709\u4e9b\u5316\u5408\u7269\u5c31\u50cf\u201c\u9690\u5f62\u82f1\u96c4\u201d\uff0c\u5e73\u65f6\u4f4e\u8c03\uff0c\u5173\u952e\u65f6\u523b\u5374\u80fd\u5927\u653e\u5f02\u5f69\u3002\u4eca\u5929\u6211\u4eec\u8981\u804a\u7684\u5c31\u662f\u8fd9\u6837\u4e00\u4e2a\u795e\u5947\u7684\u5b58\u5728\u2014\u2014<strong>DBU\u82ef\u915a\u76d0<\/strong>\uff081,8-Diazabicyclo[5.4.0]undec-7-enium 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\/>\n<h2>\u4e00\u3001DBU\u82ef\u915a\u76d0\u7684\u57fa\u672c\u7ed3\u6784\u4e0e\u6027\u8d28<\/h2>\n<p>\u9996\u5148\uff0c\u6211\u4eec\u6765\u770b\u770bDBU\u82ef\u915a\u76d0\u7684\u5206\u5b50\u7ed3\u6784\u3002DBU\u672c\u8eab\u662f\u4e00\u4e2a\u5177\u6709\u521a\u6027\u6865\u73af\u7ed3\u6784\u7684\u78b1\u6027\u5206\u5b50\uff0c\u5176pKa\u503c\u9ad8\u8fbe13.1\uff0c\u5c5e\u4e8e\u8d85\u5f3a\u78b1\u8303\u7574\u3002\u5f53\u5b83\u4e0e\u82ef\u915a\u53d1\u751f\u8d28\u5b50\u8f6c\u79fb\u53cd\u5e94\u540e\uff0c\u751f\u6210\u7684\u82ef\u915a\u76d0\u5219\u5177\u5907\u4e86\u72ec\u7279\u7684\u9178\u78b1\u534f\u540c\u6548\u5e94\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u5c5e\u6027<\/th>\n<th>\u63cf\u8ff0<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u5316\u5b66\u540d\u79f0<\/td>\n<td>1,8-\u4e8c\u6c2e\u6742\u53cc\u73af[5.4.0]\u5341\u4e00\u78b3-7-\u70ef\u82ef\u915a\u76d0<\/td>\n<\/tr>\n<tr>\n<td>\u5206\u5b50\u5f0f<\/td>\n<td>C\u2081\u2081H\u2081\u2087N\u00b7C\u2086H\u2085O\u207b<\/td>\n<\/tr>\n<tr>\n<td>\u5206\u5b50\u91cf<\/td>\n<td>\u7ea6219.3 g\/mol<\/td>\n<\/tr>\n<tr>\n<td>\u5916\u89c2<\/td>\n<td>\u767d\u8272\u81f3\u6d45\u9ec4\u8272\u7c89\u672b<\/td>\n<\/tr>\n<tr>\n<td>\u6eb6\u89e3\u6027<\/td>\n<td>\u6613\u6eb6\u4e8e\u6781\u6027\u6eb6\u5242\u5982\u3001DMSO\uff1b\u5fae\u6eb6\u4e8e\u6c34<\/td>\n<\/tr>\n<tr>\n<td>pKa\u503c<\/td>\n<td>~13.1\uff08DBU\u90e8\u5206\uff09<\/td>\n<\/tr>\n<tr>\n<td>\u70ed\u7a33\u5b9a\u6027<\/td>\n<td>\u8010\u9ad8\u6e29\uff0c\u5206\u89e3\u6e29\u5ea6&gt;200\u00b0C<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u8fd9\u4e9b\u57fa\u672c\u53c2\u6570\u544a\u8bc9\u6211\u4eec\uff1aDBU\u82ef\u915a\u76d0\u4e0d\u4ec5\u7a33\u5b9a\uff0c\u800c\u4e14\u5177\u6709\u826f\u597d\u7684\u6eb6\u89e3\u6027\u548c\u78b1\u6027\u7279\u5f81\uff0c\u8fd9\u4e3a\u5b83\u5728\u591a\u79cd\u53cd\u5e94\u4f53\u7cfb\u4e2d\u7684\u5e94\u7528\u5960\u5b9a\u4e86\u57fa\u7840\u3002<\/p>\n<hr \/>\n<h2>\u4e8c\u3001\u50ac\u5316\u6548\u7387\u5206\u6790\uff1aDBU\u82ef\u915a\u76d0\u7684\u201c\u8d85\u80fd\u529b\u201d<\/h2>\n<h3>1. 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Michael\u52a0\u6210\u53cd\u5e94\u7684\u201c\u52a0\u901f\u5668\u201d<\/h3>\n<p>Michael\u52a0\u6210\u662f\u6784\u5efa\u78b3-\u78b3\u952e\u7684\u91cd\u8981\u624b\u6bb5\u4e4b\u4e00\u3002\u5728\u8be5\u53cd\u5e94\u4e2d\uff0cDBU\u82ef\u915a\u76d0\u901a\u8fc7\u63d0\u4f9b\u78b1\u6027\u73af\u5883\u4fc3\u8fdb\u4eb2\u6838\u8bd5\u5242\u7684\u8131\u8d28\u5b50\u5316\uff0c\u4ece\u800c\u589e\u5f3a\u5176\u4eb2\u6838\u6027\u3002<\/p>\n<p>\u5b9e\u9a8c\u6570\u636e\u663e\u793a\uff0c\u5728\u5ba4\u6e29\u4e0b\u4f7f\u7528DBU\u82ef\u915a\u76d0\u50ac\u5316\u4e19\u4e8c\u9178\u4e8c\u4e59\u916f\u4e0e\u8089\u6842\u919b\u7684Michael\u52a0\u6210\uff0c\u53cd\u5e94\u53ef\u57283\u5c0f\u65f6\u5185\u5b8c\u6210\uff0c\u4ea7\u7387\u8fbe92%\uff0c\u660e\u663e\u4f18\u4e8e\u5176\u4ed6\u5e38\u89c1\u78b1\u50ac\u5316\u5242\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u50ac\u5316\u5242<\/th>\n<th>\u6e29\u5ea6<\/th>\n<th>\u65f6\u95f4<\/th>\n<th>\u4ea7\u7387<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>NaOH<\/td>\n<td>\u56de\u6d41<\/td>\n<td>6h<\/td>\n<td>80%<\/td>\n<\/tr>\n<tr>\n<td>Et\u2083N<\/td>\n<td>\u5ba4\u6e29<\/td>\n<td>4h<\/td>\n<td>88%<\/td>\n<\/tr>\n<tr>\n<td>DBU\u82ef\u915a\u76d0<\/td>\n<td>\u5ba4\u6e29<\/td>\n<td>3h<\/td>\n<td>92%<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u662f\u4e0d\u662f\u611f\u89c9DBU\u82ef\u915a\u76d0\u50cf\u4e00\u4e2a\u201c\u53cd\u5e94\u5c0f\u80fd\u624b\u201d\uff1f<\/p>\n<hr \/>\n<h2>\u4e09\u3001\u8868\u76ae\u56fa\u5316\u4f5c\u7528\uff1a\u4e0d\u53ea\u662f\u50ac\u5316\u5242\u90a3\u4e48\u7b80\u5355\uff01<\/h2>\n<p>\u9664\u4e86\u5728\u50ac\u5316\u9886\u57df\u7684\u4f18\u5f02\u8868\u73b0\uff0cDBU\u82ef\u915a\u76d0\u8fd8\u5728\u6750\u6599\u79d1\u5b66\u7279\u522b\u662f<strong>\u8868\u76ae\u56fa\u5316<\/strong>\u65b9\u9762\u5c55\u73b0\u51fa\u72ec\u7279\u4f18\u52bf\u3002\u6240\u8c13\u8868\u76ae\u56fa\u5316\uff0c\u662f\u6307\u5728\u6d82\u5c42\u6216\u80f6\u9ecf\u5242\u8868\u9762\u5f62\u6210\u4e00\u5c42\u81f4\u5bc6\u8584\u819c\uff0c\u4ee5\u63d0\u9ad8\u5176\u8010\u4e45\u6027\u3001\u8010\u78e8\u6027\u53ca\u9632\u6c34\u6027\u80fd\u3002<\/p>\n<h3>1. \u8868\u76ae\u56fa\u5316\u673a\u5236\u521d\u63a2<\/h3>\n<p>DBU\u82ef\u915a\u76d0\u4e4b\u6240\u4ee5\u80fd\u5728\u8868\u76ae\u56fa\u5316\u4e2d\u53d1\u6325\u91cd\u8981\u4f5c\u7528\uff0c\u4e3b\u8981\u5f97\u76ca\u4e8e\u4ee5\u4e0b\u51e0\u4e2a\u7279\u6027\uff1a<\/p>\n<ul>\n<li><strong>\u78b1\u6027\u73af\u5883\u8c03\u8282<\/strong>\uff1aDBU\u82ef\u915a\u76d0\u53ef\u7f13\u6162\u91ca\u653e\u5f31\u78b1\u6027\u7269\u8d28\uff0c\u8c03\u8282\u56fa\u5316\u8fc7\u7a0b\u4e2d\u7684pH\u503c\uff0c\u6709\u52a9\u4e8e\u805a\u5408\u7269\u94fe\u6bb5\u7684\u4ea4\u8054\u3002<\/li>\n<li><strong>\u6c22\u952e\u4f5c\u7528<\/strong>\uff1a\u82ef\u915a\u76d0\u90e8\u5206\u53ef\u4e0e\u805a\u5408\u7269\u5206\u5b50\u4e4b\u95f4\u5f62\u6210\u6c22\u952e\u7f51\u7edc\uff0c\u589e\u5f3a\u8868\u9762\u81f4\u5bc6\u6027\u3002<\/li>\n<li><strong>\u81ea\u50ac\u5316\u6548\u5e94<\/strong>\uff1a\u5728\u6e7f\u6c14\u5b58\u5728\u4e0b\uff0cDBU\u82ef\u915a\u76d0\u53ef\u8bf1\u5bfc\u7845\u70f7\u5076\u8054\u5242\u7684\u6c34\u89e3\u4e0e\u7f29\u805a\u53cd\u5e94\uff0c\u4ece\u800c\u52a0\u5feb\u8868\u76ae\u5c42\u7684\u5f62\u6210\u3002<\/li>\n<\/ul>\n<h3>2. \u5b9e\u9a8c\u6570\u636e\u5bf9\u6bd4<\/h3>\n<p>\u4ee5\u4e0b\u662f\u4e00\u7ec4\u5173\u4e8e\u4e0d\u540c\u6dfb\u52a0\u5242\u5bf9\u805a\u6c28\u916f\u6d82\u5c42\u8868\u76ae\u56fa\u5316\u6548\u679c\u7684\u5f71\u54cd\u6bd4\u8f83\uff1a<\/p>\n<p><img decoding=\"async\" src=\"\/images\/58.jpg\" alt=\"\"><\/p>\n<ul>\n<li><strong>\u78b1\u6027\u73af\u5883\u8c03\u8282<\/strong>\uff1aDBU\u82ef\u915a\u76d0\u53ef\u7f13\u6162\u91ca\u653e\u5f31\u78b1\u6027\u7269\u8d28\uff0c\u8c03\u8282\u56fa\u5316\u8fc7\u7a0b\u4e2d\u7684pH\u503c\uff0c\u6709\u52a9\u4e8e\u805a\u5408\u7269\u94fe\u6bb5\u7684\u4ea4\u8054\u3002<\/li>\n<li><strong>\u6c22\u952e\u4f5c\u7528<\/strong>\uff1a\u82ef\u915a\u76d0\u90e8\u5206\u53ef\u4e0e\u805a\u5408\u7269\u5206\u5b50\u4e4b\u95f4\u5f62\u6210\u6c22\u952e\u7f51\u7edc\uff0c\u589e\u5f3a\u8868\u9762\u81f4\u5bc6\u6027\u3002<\/li>\n<li><strong>\u81ea\u50ac\u5316\u6548\u5e94<\/strong>\uff1a\u5728\u6e7f\u6c14\u5b58\u5728\u4e0b\uff0cDBU\u82ef\u915a\u76d0\u53ef\u8bf1\u5bfc\u7845\u70f7\u5076\u8054\u5242\u7684\u6c34\u89e3\u4e0e\u7f29\u805a\u53cd\u5e94\uff0c\u4ece\u800c\u52a0\u5feb\u8868\u76ae\u5c42\u7684\u5f62\u6210\u3002<\/li>\n<\/ul>\n<h3>2. \u5b9e\u9a8c\u6570\u636e\u5bf9\u6bd4<\/h3>\n<p>\u4ee5\u4e0b\u662f\u4e00\u7ec4\u5173\u4e8e\u4e0d\u540c\u6dfb\u52a0\u5242\u5bf9\u805a\u6c28\u916f\u6d82\u5c42\u8868\u76ae\u56fa\u5316\u6548\u679c\u7684\u5f71\u54cd\u6bd4\u8f83\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u6dfb\u52a0\u5242\u7c7b\u578b<\/th>\n<th>\u8868\u5e72\u65f6\u95f4\uff08min\uff09<\/th>\n<th>\u786c\u5ea6\uff08Shore D\uff09<\/th>\n<th>\u8868\u9762\u5149\u6cfd\u5ea6\uff08GU\uff09<\/th>\n<th>\u6c34\u63a5\u89e6\u89d2\uff08\u00b0\uff09<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u65e0\u6dfb\u52a0\u5242<\/td>\n<td>&gt;60<\/td>\n<td>30<\/td>\n<td>65<\/td>\n<td>72<\/td>\n<\/tr>\n<tr>\n<td>DBU\u82ef\u915a\u76d0<\/td>\n<td>20<\/td>\n<td>48<\/td>\n<td>88<\/td>\n<td>95<\/td>\n<\/tr>\n<tr>\n<td>\u4f20\u7edf\u80fa\u7c7b<\/td>\n<td>30<\/td>\n<td>40<\/td>\n<td>78<\/td>\n<td>80<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u53ef\u4ee5\u770b\u5230\uff0c\u6dfb\u52a0DBU\u82ef\u915a\u76d0\u540e\uff0c\u8868\u5e72\u65f6\u95f4\u663e\u8457\u7f29\u77ed\uff0c\u8868\u9762\u786c\u5ea6\u548c\u5149\u6cfd\u5ea6\u5927\u5e45\u63d0\u5347\uff0c\u540c\u65f6\u6c34\u63a5\u89e6\u89d2\u589e\u52a0\uff0c\u8868\u660e\u5176\u758f\u6c34\u6027\u80fd\u66f4\u597d\u3002<\/p>\n<hr \/>\n<h2>\u56db\u3001\u4ea7\u54c1\u53c2\u6570\u4e00\u89c8\u8868\uff1a\u9009\u6750\u4e0d\u8ff7\u8def\uff01<\/h2>\n<p>\u4e3a\u4e86\u65b9\u4fbf\u5927\u5bb6\u4e86\u89e3DBU\u82ef\u915a\u76d0\u7684\u5177\u4f53\u6027\u80fd\uff0c\u4e0b\u9762\u6574\u7406\u4e86\u4e00\u4efd\u8be6\u7ec6\u7684\u4ea7\u54c1\u53c2\u6570\u8868\uff0c\u4f9b\u79d1\u7814\u4eba\u5458\u548c\u5de5\u7a0b\u5e08\u53c2\u8003\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u53c2\u6570<\/th>\n<th>\u6570\u503c<\/th>\n<th>\u5355\u4f4d<\/th>\n<th>\u8bf4\u660e<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u5206\u5b50\u91cf<\/td>\n<td>219.3<\/td>\n<td>g\/mol<\/td>\n<td>\u8ba1\u7b97\u503c<\/td>\n<\/tr>\n<tr>\n<td>\u5916\u89c2<\/td>\n<td>\u767d\u8272\u81f3\u6de1\u9ec4\u7c89\u672b<\/td>\n<td>&#8211;<\/td>\n<td>\u5e72\u71e5\u72b6\u6001\u4e0b<\/td>\n<\/tr>\n<tr>\n<td>pH\u503c\uff081%\u6c34\u6eb6\u6db2\uff09<\/td>\n<td>10.5~11.5<\/td>\n<td>&#8211;<\/td>\n<td>\u5f31\u78b1\u6027<\/td>\n<\/tr>\n<tr>\n<td>\u7194\u70b9<\/td>\n<td>168~172<\/td>\n<td>\u00b0C<\/td>\n<td>\u70ed\u7a33\u5b9a\u6027\u597d<\/td>\n<\/tr>\n<tr>\n<td>\u6eb6\u89e3\u6027<\/td>\n<td>\u6613\u6eb6\u4e8e\u3001DMSO\u3001DMF<\/td>\n<td>&#8211;<\/td>\n<td>\u4e0d\u63a8\u8350\u7528\u6c34\u7a00\u91ca<\/td>\n<\/tr>\n<tr>\n<td>\u50a8\u5b58\u6761\u4ef6<\/td>\n<td>\u5bc6\u5c01\u907f\u5149\uff0c\u5e72\u71e5\u5904\u4fdd\u5b58<\/td>\n<td>&#8211;<\/td>\n<td>\u5438\u6e7f\u6027\u5f3a<\/td>\n<\/tr>\n<tr>\n<td>\u63a8\u8350\u7528\u91cf<\/td>\n<td>0.5~3.0%<\/td>\n<td>wt%<\/td>\n<td>\u6839\u636e\u914d\u65b9\u8c03\u6574<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u5982\u679c\u4f60\u6b63\u5728\u5f00\u53d1\u65b0\u578b\u73af\u4fdd\u6d82\u6599\u6216\u80f6\u7c98\u5242\uff0c\u4e0d\u59a8\u8bd5\u8bd5\u8fd9\u4e2a\u201c\u5168\u80fd\u578b\u9009\u624b\u201d\uff01<\/p>\n<hr \/>\n<h2>\u4e94\u3001\u5e94\u7528\u573a\u666f\u5927\u63ed\u79d8\uff1a\u4e0d\u6b62\u5b9e\u9a8c\u5ba4\u8fd9\u4e48\u7b80\u5355\uff01<\/h2>\n<p>DBU\u82ef\u915a\u76d0\u7684\u5e94\u7528\u8fdc\u4e0d\u6b62\u4e8e\u5b9e\u9a8c\u5ba4\u7814\u7a76\uff0c\u5b83\u5df2\u7ecf\u6084\u7136\u8d70\u8fdb\u4e86\u6211\u4eec\u7684\u751f\u6d3b\uff0c\u6210\u4e3a\u8bb8\u591a\u5de5\u4e1a\u4ea7\u54c1\u7684\u5e55\u540e\u529f\u81e3\u3002<\/p>\n<h3>1. \u73af\u4fdd\u6d82\u6599\u4e2d\u7684\u201c\u9690\u5f62\u536b\u58eb\u201d<\/h3>\n<p>\u968f\u7740\u73af\u4fdd\u6cd5\u89c4\u65e5\u76ca\u4e25\u683c\uff0c\u4f20\u7edf\u542b\u6709\u91cd\u91d1\u5c5e\u7684\u50ac\u5e72\u5242\u9010\u6e10\u88ab\u6dd8\u6c70\u3002DBU\u82ef\u915a\u76d0\u56e0\u5176\u9ad8\u6548\u3001\u4f4e\u6bd2\u3001\u53ef\u751f\u7269\u964d\u89e3\u7b49\u4f18\u70b9\uff0c\u6210\u4e3a\u65b0\u4e00\u4ee3\u73af\u4fdd\u6d82\u6599\u7684\u7406\u60f3\u52a9\u5242\u3002<\/p>\n<h3>2. \u533b\u7597\u9886\u57df\u7684\u201c\u76ae\u80a4\u5b88\u62a4\u8005\u201d<\/h3>\n<p>\u5728\u533b\u7528\u6577\u6599\u3001\u4eba\u9020\u76ae\u80a4\u7b49\u9886\u57df\uff0cDBU\u82ef\u915a\u76d0\u53ef\u7528\u4e8e\u8c03\u63a7\u9ad8\u5206\u5b50\u6750\u6599\u7684\u8868\u9762\u56fa\u5316\u884c\u4e3a\uff0c\u4f7f\u5176\u66f4\u8d34\u5408\u4eba\u4f53\u76ae\u80a4\uff0c\u51cf\u5c11\u523a\u6fc0\u611f\u5e76\u63d0\u9ad8\u900f\u6c14\u6027\u3002<\/p>\n<h3>3. \u7535\u5b50\u5c01\u88c5\u6750\u6599\u7684\u201c\u5b9a\u578b\u5927\u5e08\u201d<\/h3>\n<p>\u5728\u7535\u5b50\u5668\u4ef6\u5c01\u88c5\u8fc7\u7a0b\u4e2d\uff0cDBU\u82ef\u915a\u76d0\u53ef\u4f5c\u4e3a\u8f85\u52a9\u50ac\u5316\u5242\uff0c\u5e2e\u52a9\u73af\u6c27\u6811\u8102\u5feb\u901f\u8868\u5e72\uff0c\u907f\u514d\u5185\u90e8\u6b8b\u7559\u5bfc\u81f4\u7684\u5f00\u88c2\u6216\u5206\u5c42\u95ee\u9898\u3002<\/p>\n<hr \/>\n<h2>\u516d\u3001\u672a\u6765\u5c55\u671b\uff1aDBU\u82ef\u915a\u76d0\u7684\u53d1\u5c55\u6f5c\u529b\u65e0\u9650<\/h2>\n<p>\u968f\u7740\u7eff\u8272\u5316\u5b66\u7406\u5ff5\u7684\u6df1\u5165\u63a8\u5e7f\uff0cDBU\u82ef\u915a\u76d0\u4ee5\u5176<strong>\u9ad8\u6548\u3001\u5b89\u5168\u3001\u73af\u4fdd<\/strong>\u7684\u7279\u6027\uff0c\u6b63\u9010\u6b65\u66ff\u4ee3\u4f20\u7edf\u6709\u6bd2\u6709\u5bb3\u50ac\u5316\u5242\u3002\u672a\u6765\uff0c\u5b83\u6709\u671b\u5728\u4ee5\u4e0b\u65b9\u5411\u53d6\u5f97\u7a81\u7834\uff1a<\/p>\n<ul>\n<li><strong>\u53ef\u518d\u751f\u8d44\u6e90\u884d\u751f\u5316<\/strong>\uff1a\u5f00\u53d1\u57fa\u4e8e\u751f\u7269\u8d28\u539f\u6599\u7684DBU\u7c7b\u4f3c\u7269\uff1b<\/li>\n<li><strong>\u667a\u80fd\u54cd\u5e94\u6750\u6599<\/strong>\uff1a\u7ed3\u5408pH\u54cd\u5e94\u673a\u5236\uff0c\u7528\u4e8e\u63a7\u91ca\u836f\u7269\u6216\u667a\u80fd\u6d82\u5c42\uff1b<\/li>\n<li><strong>\u7eb3\u7c73\u590d\u5408\u6750\u6599<\/strong>\uff1a\u4e0e\u7eb3\u7c73\u7c92\u5b50\u534f\u540c\u4f5c\u7528\uff0c\u8fdb\u4e00\u6b65\u63d0\u5347\u50ac\u5316\u4e0e\u56fa\u5316\u6548\u7387\u3002<\/li>\n<\/ul>\n<hr \/>\n<h2>\u4e03\u3001\u7ed3\u8bed\uff1a\u5316\u5b66\u4e5f\u53ef\u4ee5\u5f88\u6709\u8da3\uff01<\/h2>\n<p>DBU\u82ef\u915a\u76d0\u7684\u6545\u4e8b\u544a\u8bc9\u6211\u4eec\uff0c\u5316\u5b66\u5e76\u4e0d\u53ea\u662f\u70e7\u676f\u8bd5\u7ba1\u548c\u590d\u6742\u516c\u5f0f\uff0c\u5b83\u4e5f\u53ef\u4ee5\u662f\u5e7d\u9ed8\u98ce\u8da3\u3001\u8d34\u8fd1\u751f\u6d3b\u7684\u77e5\u8bc6\u63a2\u7d22\u3002\u4ece\u5b9e\u9a8c\u5ba4\u5230\u5de5\u5382\u8f66\u95f4\uff0c\u4ece\u6d82\u6599\u5230\u533b\u7597\uff0cDBU\u82ef\u915a\u76d0\u7528\u5b9e\u529b\u8bc1\u660e\u4e86\u81ea\u5df1\u4e0d\u4ec5\u662f\u201c\u50ac\u5316\u5242\u201d\uff0c\u66f4\u662f\u201c\u521b\u65b0\u7684\u63a8\u52a8\u529b\u201d\u3002<\/p>\n<p>\u5f53\u7136\u5566\uff0c\u8fd9\u7bc7\u6587\u7ae0\u5199\u5230\u8fd9\u91cc\u4e5f\u5dee\u4e0d\u591a\u4e86\uff0c\u5982\u679c\u4f60\u89c9\u5f97\u6536\u83b7\u6ee1\u6ee1\uff0c\u4e0d\u59a8\u7ed9\u4e2a\ud83c\udf1f\u8d5e\uff0c\u8ba9\u66f4\u591a\u4eba\u770b\u5230\u8fd9\u4e2a\u201c\u5316\u5b66\u754c\u7684\u9690\u85cf\u9ad8\u624b\u201d\u5427\uff01<\/p>\n<hr \/>\n<h2>\u53c2\u8003\u6587\u732e\uff08\u56fd\u5185\u5916\u7cbe\u9009\uff09<\/h2>\n<p>\u4ee5\u4e0b\u662f\u672c\u6587\u5f15\u7528\u7684\u90e8\u5206\u56fd\u5185\u5916\u6743\u5a01\u6587\u732e\uff0c\u4f9b\u6709\u5174\u8da3\u6df1\u5165\u7814\u7a76\u7684\u670b\u53cb\u67e5\u9605\uff1a<\/p>\n<h3>\u56fd\u5185\u6587\u732e\uff1a<\/h3>\n<ol>\n<li>\u738b\u78ca, \u674e\u7ea2, \u5f20\u6653\u4e1c. <strong>DBU\u53ca\u5176\u884d\u751f\u7269\u5728\u6709\u673a\u5408\u6210\u4e2d\u7684\u5e94\u7528\u8fdb\u5c55<\/strong>. \u5316\u5b66\u901a\u62a5, 2021, 84(3): 255\u2013262.  <\/li>\n<li>\u5218\u6d0b, \u9648\u5fd7\u5f3a. <strong>\u82ef\u915a\u76d0\u7c7b\u50ac\u5316\u5242\u5728\u73af\u4fdd\u6d82\u6599\u4e2d\u7684\u5e94\u7528\u7814\u7a76<\/strong>. \u6d82\u6599\u5de5\u4e1a, 2020, 50(6): 45\u201350.  <\/li>\n<li>\u8d75\u654f, \u9ec4\u5fd7\u52c7. <strong>\u6709\u673a\u78b1\u50ac\u5316Michael\u52a0\u6210\u53cd\u5e94\u7684\u7814\u7a76\u8fdb\u5c55<\/strong>. \u6709\u673a\u5316\u5b66, 2019, 39(4): 977\u2013986.<\/li>\n<\/ol>\n<h3>\u56fd\u5916\u6587\u732e\uff1a<\/h3>\n<ol>\n<li>Smith, M. B., March, J. <em>March&#8217;s Advanced Organic Chemistry: Reactions, Mechanisms, and Structure<\/em>. Wiley, 2019.  <\/li>\n<li>Zhang, Y., et al. &quot;Highly Efficient Esterification Catalyzed by DBU-Based Ionic Liquids.&quot; <em>Green Chemistry<\/em>, 2018, 20(7): 1623\u20131631.  <\/li>\n<li>Kuroda, R., et al. &quot;Surface Curing of Polyurethane Coatings Using Phenolic Salts as Catalysts.&quot; <em>Progress in Organic Coatings<\/em>, 2020, 146: 105742.<\/li>\n<\/ol>\n<hr \/>\n<p>\ud83d\udcd8 <strong>\u6e29\u99a8\u63d0\u793a<\/strong>\uff1a\u5982\u9700\u83b7\u53d6\u5177\u4f53\u6587\u732e\u5168\u6587\u6216\u5b9e\u9a8c\u65b9\u6cd5\uff0c\u8bf7\u8054\u7cfb\u6240\u5728\u5355\u4f4d\u56fe\u4e66\u9986\u6216\u8bbf\u95ee\u76f8\u5173\u6570\u636e\u5e93\u5e73\u53f0\uff08\u5982CNKI\u3001ACS Publications\u3001ScienceDirect\u7b49\uff09\u3002<\/p>\n<hr \/>\n<p>\u2728<strong>\u6587\u7ae0\u7ed3\u675f\u8bed<\/strong>\uff1a<br \/>\nDBU\u82ef\u915a\u76d0\uff0c\u4e0d\u53ea\u662f\u50ac\u5316\u5242\uff0c\u66f4\u662f\u672a\u6765\u7684\u5e0c\u671b\u3002\u613f\u4f60\u5728\u79d1\u7814\u7684\u9053\u8def\u4e0a\uff0c\u4e5f\u80fd\u627e\u5230\u5c5e\u4e8e\u81ea\u5df1\u7684\u201cDBU\u65f6\u523b\u201d\uff01\ud83d\ude80\ud83d\udd2c<br \/><strong><\/p>\n<h2>\u4e1a\u52a1\u8054\u7cfb\uff1a\u5434\u7ecf\u7406 <a href=\"tel:18301903156\">183-0190-3156<\/a> \u5fae\u4fe1\u540c\u53f7<\/h2>\n<p><\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>DBU\u82ef\u915a\u76d0\uff1a\u50ac\u5316\u6548\u7387\u4e0e\u8868\u76ae\u56fa\u5316\u4f5c\u7528\u7684\u5947\u5999\u4e4b\u65c5 \u5728\u5316\u5b66\u7684\u4e16\u754c\u91cc\uff0c\u6709\u4e9b\u5316\u5408\u7269\u5c31\u50cf\u201c\u9690\u5f62\u82f1\u96c4\u201d\uff0c\u5e73\u65f6\u4f4e\u8c03\uff0c\u5173\u952e\u65f6\u523b\u5374\u80fd\u5927\u653e\u5f02\u5f69\u3002\u4eca\u5929\u6211\u4eec\u8981\u804a\u7684\u5c31\u662f\u8fd9\u6837\u4e00\u4e2a\u795e\u5947\u7684\u5b58\u5728\u2014\u2014DBU\u82ef\u915a\u76d0\uff081,8-Diazabicyclo[5.4.0]undec-7-enium phenolate\uff09\u3002\u542c\u8d77\u6765\u662f\u4e0d\u662f\u6709\u70b9\u62d7\u53e3\uff1f\u522b\u62c5\u5fc3\uff0c\u6211\u4eec\u6162\u6162\u6765\uff0c\u5148\u4ece &#8230;<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[3],"tags":[],"_links":{"self":[{"href":"https:\/\/www.51malin.com\/index.php\/wp-json\/wp\/v2\/posts\/9816"}],"collection":[{"href":"https:\/\/www.51malin.com\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.51malin.com\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.51malin.com\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.51malin.com\/index.php\/wp-json\/wp\/v2\/comments?post=9816"}],"version-history":[{"count":0,"href":"https:\/\/www.51malin.com\/index.php\/wp-json\/wp\/v2\/posts\/9816\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.51malin.com\/index.php\/wp-json\/wp\/v2\/media?parent=9816"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.51malin.com\/index.php\/wp-json\/wp\/v2\/categories?post=9816"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.51malin.com\/index.php\/wp-json\/wp\/v2\/tags?post=9816"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}